Hydroxylamine → N'-hydroxyoctanimidamide

HRID 1174475Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1174475
[C:1](#[N:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[NH2:10][OH:11]>O.CCO>[OH:11][N:10]=[C:1]([NH2:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Komponenten

5

Edukt 2

HCID 787HydroxylamineHCID 31286Octanenitrile

Produkt 1

HCID 3661326N'-hydroxyoctanimidamideAusbeute 74,6 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 702EthanolLösungsmittelHCID 962WaterLösungsmittel2×

Versuchsvorschrift

Octanonitrile (1 g, 7.99 mmol) and hydroxylamine (50% in water, 0.74 cm3, 0.79 a 12 mmol, 1.5 eq) in EtOH (1 cm3) were stirred at room temperature for 7 days. Water (10 cm3) was then added. This caused crystals to precipitate, these were collected by filtration and dried in high vacuum line to give the product N′-hydroxyoctanimidamide (0.94 g, 74.6%) as a white solid, mp 73-75° C.

Aufarbeitung

  1. customThis caused crystals to precipitate
  2. filtrationthese were collected by filtration
  3. customdried in high vacuum line

Quellen und Nachweise

ORD-Eintrag
ord-cde784457b514c409686c3e92bbfa8e1
Quelldatensatz
uspto-grants-2010_11
Patentnummer
US07838483B2

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