Anisole → HCID 178503585, Verbindung

HRID 1194297Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1194297
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:6](=[CH:12][CH:13]=1)[N:7]=[C:8]([S:10][CH3:11])[N:9]=2.[C:14]1(OC)C=CC=CC=1.[F:22][C:23]([F:30])([F:29])[S:24]([O:27]C)(=[O:26])=[O:25]>C(OCC)(=O)C>[F:22][C:23]([F:30])([F:29])[S:24]([O-:27])(=[O:26])=[O:25].[CH3:14][N:9]1[C:5]2=[CH:4][CH:3]=[C:2]([CH3:1])[CH:13]=[CH:12][C:6]2=[NH+:7][CH:8]1[S:10][CH3:11]

Komponenten

5

Edukt 3

HCID 7519AnisoleHCID 9526Methyl triflateHCID 200643756-Methyl-2-(methylsulfanyl)cyclohepta[d]imidazole

Produkt 1

HCID 178503585HCID 178503585, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8857Ethyl AcetateLösungsmittel

Versuchsvorschrift

6-Methyl-2-methylthiocycloheptimidazole (27 g) was added to 100 ml of anisole and stirred under ice cooling. Then, 28 g of methyl trifluoromethanesulfonate was added dropwise thereto, and stirred under ice cooling. The mixture was further stirred at room temperature for one hour, 200 ml of ethyl acetate was added, and deposited crystals were collected by filtration and dried.

Aufarbeitung

  1. stirringstirred under ice cooling
  2. stirringThe mixture was further stirred at room temperature for one hour
  3. filtrationwere collected by filtration
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-75cb94b97c944c6da485b398bf71388d
Quelldatensatz
uspto-grants-1989_03
Patentnummer
US04814265

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