Potassium Carbonate → Bis(di-p-tolylamino)benzo[a]perylene

HRID 1245252Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1245252
[C:1]1([CH3:15])[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.C(=O)([O-])[O-].[K+].[K+].Br[C:23]1[CH:24]=[C:25]2[C:42]3[C:39]([C:40]=1Br)=[CH:38][CH:37]=[CH:36][C:35]=3[C:34]1[C:43]3[C:30]([CH:31]=[C:32]4[CH:47]=[CH:46][CH:45]=[CH:44][C:33]4=1)=[CH:29][CH:28]=[CH:27][C:26]2=3>O.[Cu]>[C:11]1([CH3:14])[CH:12]=[CH:13][C:8]([N:7]([C:23]2[CH:24]=[C:25]3[C:42]4[C:39]([C:40]=2[N:7]([C:8]2[CH:9]=[CH:10][C:11]([CH3:14])=[CH:12][CH:13]=2)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:38][CH:37]=[CH:36][C:35]=4[C:34]2[C:43]4[C:30]([CH:31]=[C:32]5[CH:47]=[CH:46][CH:45]=[CH:44][C:33]5=2)=[CH:29][CH:28]=[CH:27][C:26]3=4)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:9][CH:10]=1

Komponenten

6

Edukt 3

HCID 11430Potassium CarbonateHCID 69293Benzenamine, 4-methyl-N-(4-methylphenyl)-HCID 21910019Dibromobenzo[a]perylene

Produkt 1

HCID 21910029Bis(di-p-tolylamino)benzo[a]perylene

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23978CopperKatalysatorHCID 962WaterLösungsmittel

Versuchsvorschrift

Then, two equivalents of di-p-tolylamine, potassium carbonate, and copper power were added to the thus obtained dibromobenzo[a]perylene. This mixture stood still for reaction at 200 degrees centigrade for thirty hours. After reactant solution was diluted with water, reactant was extracted by chloroform. Thereafter, the reactant was refined in a conventional manner to thereby obtain bis(di-p-tolylamino)benzo[a]perylene.

Aufarbeitung

  1. customThis mixture stood still for reaction at 200 degrees centigrade for thirty hours
  2. extractionwas extracted by chloroform

Quellen und Nachweise

ORD-Eintrag
ord-0af6786593064068bc78cff2983b6753
Quelldatensatz
uspto-grants-2006_10
Patentnummer
US07125614B2

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