Hydroxyamine hydrochloride → Hydrochloric Acid

HRID 128048

Reaktionsgleichung

Reaktionsgleichung von HRID 128048
[CH2:1]([C:3]1([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:14][CH:13]=[CH:12][CH2:11][CH2:10][CH:9]=[CH:8][CH2:7][CH:6]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[N:5]=[CH:4]1)[CH3:2].[ClH:25].[NH2:26][OH:27]>O>[ClH:25].[CH2:1]([C:3]([CH2:21][CH2:22][CH2:23][CH3:24])([CH2:14][CH:13]=[CH:12][CH2:11][CH2:10][CH:9]=[CH:8][CH2:7][CH:6]([C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)[NH2:5])[CH:4]=[N:26][OH:27])[CH3:2].[C:15]1([CH:6]([NH2:5])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][C:3]([CH2:1][CH3:2])([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:4][NH2:26])[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Komponenten

6

Edukt 2

HCID 443297Hydroxyamine hydrochlorideHCID 545232413-Ethyl-3-n-butyl-12-phenyl-1-aza-1,5,9-cyclododecatriene

Produkt 3

HCID 313Hydrochloric AcidHCID 204360921-Phenyl-10-ethyl-10-n-butyl-1,11-diaminoundecaneHCID 736789192-Ethyl-2-n-butyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Reaction of 3-ethyl-3-n-butyl-12-phenyl-1-aza-1,5,9-cyclododecatriene with hydroxylamine hydrochloride, in the presence of hydrochloric acid and water, to 2-ethyl-2-n-butyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime, and hydrogenation of this to yield 1-phenyl-10-ethyl-10-n-butyl-1,11-diaminoundecane; b.p. 155°-158° C./5 Pa; nD20 =1.5045.

Quellen und Nachweise

ORD-Eintrag
ord-bc27ecb4f0ac4fd6b339612ca059bddf
Quelldatensatz
uspto-grants-1981_03
Patentnummer
US04258176

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