Reaktionsgleichung
[C:1]([C:5]1[CH:11]=[CH:10][C:8]([NH2:9])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[F:12][B-:13]([F:16])([F:15])[F:14].[N:17]#[O+].[K+].[Br-]>C(#N)C.C(Cl)Cl>[F:12][B-:13]([F:16])([F:15])[F:14].[C:1]([C:5]1[CH:6]=[CH:7][C:8]([N+:9]#[N:17])=[CH:10][CH:11]=1)([CH3:4])([CH3:2])[CH3:3]Komponenten
6
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
The 4-tert-butylaniline was dissolved in a 1:1 mixture of acetonitrile and dry methylene chloride prior to addition to the nitrosonium tetrafluoroborate. Yield: 78%. MP 91° C. IR (KBr) 3364.8, 3107.3, 2968.6, 2277.2, 1579.2, 1482.0, 1418.0, 1373.5, 1269.8, 1056.9, 841.1, 544.6, 621.4 cm−1. 1H NMR (400 MHz, CD3CN) δ 8.16 (ABq, J=9.0 Hz, Δv=298.7 Hz, 4H), 1.30 (s, 12H). 13C NMR (100 MHz, CD3CN) δ 168.85, 133.67, 130.43, 111.88, 37.86, 30.84.
Quellen und Nachweise
- ORD-Eintrag
- ord-bde4a78e629a447c9d030bbda46436df
- Quelldatensatz
- uspto-grants-2008_06
- Patentnummer
- US07384815B2
Verknüpfte Notizen
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