1,3,2-Dioxathiolane, 2,2-dioxide → Cyclohexylamine

HRID 1413202

Reaktionsgleichung

Reaktionsgleichung von HRID 1413202
Cl.C[NH:3][CH2:4][CH2:5][CH:6](C1C=CC=CC=1)[C:7]1C=CC=[CH:9][CH:8]=1.[S:19]1([O:25][CH2:24][CH2:23][O:22]1)(=[O:21])=[O:20].[CH2:26]([Li:30])[CH2:27][CH2:28][CH3:29]>>[Li+:30].[S:19]([O-:25])([O:22][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])(=[O:21])=[O:20].[CH:24]1([NH2:3])[CH2:23][CH2:29][CH2:28][CH2:27][CH2:26]1

Komponenten

5

Edukt 3

HCID 140751,3,2-Dioxathiolane, 2,2-dioxideHCID 21467371N-Methyl-gamma-phenyl-benzenepropanamine hydrochloride (1:1)HCID 178418339Butyllithium

Produkt 2

HCID 7965CyclohexylamineHCID 23693704HCID 23693704, Verbindung

Versuchsvorschrift

N-methyl-3,3-diphenyl-propylamine hydrochloride, m.p. 159°-61° C. By a procedure analogous to that given above ethylene sulphate is reacted with butyllithium to give n-hexyl sulphate lithium salt which with cyclohexylamine gives N-cyclohexyl-n-hexylamine (b.p. 66° C./0.6).

Quellen und Nachweise

ORD-Eintrag
ord-3aaa0806a3534c77a7e2bc244df9db2b
Quelldatensatz
uspto-grants-1981_02
Patentnummer
US04249003

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