9,10-Anthracenedione, 2-amino-3-chloro- → Anthrimide

HRID 1414218

Reaktionsgleichung

Reaktionsgleichung von HRID 1414218
[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5](Cl)=[CH:4][CH:3]=1.S(Cl)(Cl)=O.[N+](C1C=CC=CC=1)([O-])=O.C(=O)([O-])[O-].[Na+].[Na+].N[C:39]1[C:52]2[C:51](=[O:53])[C:50]3[C:45](=[CH:46][CH:47]=[CH:48][CH:49]=3)[C:44](=[O:54])[C:43]=2[CH:42]=[C:41](Cl)[CH:40]=1>>[CH:10]1[CH:9]=[C:8]2[C:7]([C:6]3[CH:5]=[CH:4][CH:3]=[C:2]([NH:1][C:42]4[C:43]5[C:44]([C:45]6[C:50]([C:51](=[O:53])[C:52]=5[CH:39]=[CH:40][CH:41]=4)=[CH:49][CH:48]=[CH:47][CH:46]=6)=[O:54])[C:15]=3[C:14](=[O:16])[C:13]2=[CH:12][CH:11]=1)=[O:17]

Komponenten

6

Edukt 5

HCID 67719,10-Anthracenedione, 2-amino-3-chloro-HCID 7416NitrobenzeneHCID 10340Sodium CarbonateHCID 178841-Amino-4-chloro-9,10-anthracenedioneHCID 24386Thionyl Chloride

Produkt 1

HCID 6700Anthrimide

Versuchsvorschrift

21 g of 6-chloro-2-(4-diphenyl)-anthrapyrimidine (obtained by reacting 1-amino-4-chloroanthraquinone with diphenyl-4-carboxylic acid N-methylamide in the presence of thionyl chloride (in accordance with D.R.P. 566,474)) are condensed, in accordance with Example 1, in 250 parts of nitrobenzene in the presence of 7.5 parts of sodium carbonate and 0.25 part of copper-1 chloride with 13.5 parts of 1-amino-3-chloroanthraquinone. 28 parts are obtained of the anthrimide of the formula ##SPC9##

Aufarbeitung

  1. customcondensed

Quellen und Nachweise

ORD-Eintrag
ord-9382bbe1a6aa4dd395b41c896390f9e5
Quelldatensatz
uspto-grants-1977_01
Patentnummer
US04001170

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