Water → 3-(Nitro-n-butylamino)benzophenone

HRID 1439788Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1439788
Cl[C:2]1[CH:15]=[CH:14][C:5]([C:6]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[O:7])=[CH:4][C:3]=1[N+:16]([O-])=O.[CH2:19](N)[CH2:20][CH2:21][CH3:22].O.[N+:25](C1C=C(C=CC=1NCCCC)C(C1C=CC=CC=1)=O)([O-:27])=[O:26]>C1(C)C=CC=CC=1>[N+:25]([N:16]([CH2:19][CH2:20][CH2:21][CH3:22])[C:3]1[CH:4]=[C:5]([CH:14]=[CH:15][CH:2]=1)[C:6]([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)=[O:7])([O-:27])=[O:26]

Komponenten

6

Edukt 4

HCID 962WaterHCID 8007ButylamineHCID 417434-Chloro-3-nitrobenzophenoneHCID 6205244-n-Butylamino-3-nitrobenzophenone

Produkt 1

HCID 205552293-(Nitro-n-butylamino)benzophenone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Versuchsvorschrift

A mixture of 4-chloro-3-nitrobenzophenone (13.08 g.; 0.05 mole) and n-butylamine (10.97 g.; 0.15 mole) are refluxed and stirred for 4 hours. To the reaction mixture is added water (300 ml.) and toluene (200 ml.) and the toluene layer collected and dried over magnesium sulfate. The toluene solution is filtered and the toluene removed under vacuum to afford 11.4 g. of 3-nitro-4-n-butylaminobenzophenone.

Aufarbeitung

  1. temperatureare refluxed
  2. customthe toluene layer collected
  3. dry with materialdried over magnesium sulfate
  4. filtrationThe toluene solution is filtered
  5. customthe toluene removed under vacuum
  6. customto afford 11.4 g

Quellen und Nachweise

ORD-Eintrag
ord-e97de0f6d624432391909d664805b238
Quelldatensatz
uspto-grants-1977_11
Patentnummer
US04060636

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