Water → 6-(3-Methoxynaphthalen-2-yl)-1,3,5-triazine-2,4(1H,3H)-diimine

HRID 1583866Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1583866
[CH3:1][O:2][C:3]1[C:12]([C:13]#[N:14])=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1.[C:15]([NH:17][C:18]([NH2:20])=[NH:19])#[N:16].[OH-].[K+].O>COCCO>[NH2:16][C:15]1[N:17]=[C:18]([NH2:20])[N:19]=[C:13]([C:12]2[C:3]([O:2][CH3:1])=[CH:4][C:5]3[C:10]([CH:11]=2)=[CH:9][CH:8]=[CH:7][CH:6]=3)[N:14]=1

Komponenten

6

Edukt 4

HCID 962WaterHCID 14797Potassium HydroxideHCID 133737273-Methoxynaphthalene-2-carbonitrileHCID 178418324HCID 178418324, Verbindung

Produkt 1

HCID 119710966-(3-Methoxynaphthalen-2-yl)-1,3,5-triazine-2,4(1H,3H)-diimine

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 80192-MethoxyethanolLösungsmittel

Versuchsvorschrift

A mixture of 3.24 grams of 2-methoxy-3-naphthonitrile, 2.23 grams of cyanoguanidine and 0.24 gram of KOH was dissolved in 30 ml of methyl cellosolve with heating and the mixture was heated to reflux for 6.5 hours. After the reaction was completed, the reaction solution was was poured into water, the crystals separated out were taken by filtration, and were recrystallized from ethyl alcohol to give 2,4-diamino-6-(2-methoxy-3-naphthyl)-s-triazine, colourless needles, melting point 243° to 244° C., the yield being 4.12 grams.

Aufarbeitung

  1. temperaturewith heating
  2. temperaturethe mixture was heated
  3. temperatureto reflux for 6.5 hours
  4. customthe crystals separated out
  5. filtrationwere taken by filtration
  6. customwere recrystallized from ethyl alcohol

Quellen und Nachweise

ORD-Eintrag
ord-514aed68da6e412e8ff3f36d28763527
Quelldatensatz
uspto-grants-1985_11
Patentnummer
US04554275

Notizen zur Reaktion

Wird geladen…