Acetonitrile → 1-(2-Cyanophenyliminomethyl)-2-nitroiminoimidazolidine

HRID 1587744Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1587744
C(O[CH:4](OCC)[N:5]1[CH2:9][CH2:8][NH:7][C:6]1=[N:10][N+:11]([O-:13])=[O:12])C.[NH2:17][C:18]1[CH:25]=[CH:24][CH:23]=[CH:22][C:19]=1[C:20]#[N:21].C(#N)C>CCOCC>[C:20]([C:19]1[CH:22]=[CH:23][CH:24]=[CH:25][C:18]=1[N:17]=[CH:4][N:5]1[CH2:9][CH2:8][NH:7][C:6]1=[N:10][N+:11]([O-:13])=[O:12])#[N:21]

Komponenten

5

Edukt 3

HCID 6342AcetonitrileHCID 729132-AminobenzonitrileHCID 1364034191-Diethoxymethyl-2-nitroiminoimidazolidine

Produkt 1

HCID 1363314871-(2-Cyanophenyliminomethyl)-2-nitroiminoimidazolidineAusbeute 98,9 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

0.05 g of boron trifluoride ether complex was added to a mixture of 2.0 g of 1-diethoxymethyl-2-nitroiminoimidazolidine, 1.02 g of o-aminobenzonitrile and 5 ml of acetonitrile followed by agitation at room temperature for 5 minutes. Ether was added to the reaction mixture, and the resultant crystals were collected by filtration and dried to give 2.2 g of 1-(2-cyanophenyliminomethyl)-2-nitroiminoimidazolidine.

Aufarbeitung

  1. filtrationthe resultant crystals were collected by filtration
  2. customdried

Quellen und Nachweise

ORD-Eintrag
ord-eb5102ebd66b4f9b988812b5800e0aa3
Quelldatensatz
uspto-grants-1993_06
Patentnummer
US05219868

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