Aldoxime → Acetonitrile oxide

HRID 1606003Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1606003
ClCl.[CH:3](=[N:5][OH:6])[CH3:4].C(=O)(O)[O-].[Na+].[Cl:12][C:13]1[C:14](=[O:21])[CH:15]=[CH:16][C:17](=[O:20])[C:18]=1[Cl:19]>O>[C:3](#[N+:5][O-:6])[CH3:4].[Cl:12][C:13]1[C:14](=[O:21])[C:15]2[C:3]([CH3:4])=[N:5][O:6][C:16]=2[C:17](=[O:20])[C:18]=1[Cl:19]

Komponenten

7

Edukt 4

HCID 7863AldoximeHCID 24526ChlorineHCID 1384232,3-Dichloro-1,4-benzoquinoneHCID 516892Sodium Bicarbonate

Produkt 2

HCID 522391Acetonitrile oxideHCID 21545721HCID 21545721, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

A solution of acetonitrile oxide was prepared by passing chlorine (10.8 grams) over 30 minutes into a stirred suspension of acetaldoxime (9 grams) and sodium bicarbonate (25.2 grams) in water at 0° C was added 2,3-dichlorobenzoquinone (17.7 grams) portionwise over 15 minutes. The mixture was stirred at 0°-5° C for 2 hours and then extracted with methylene chloride. The dried extracts were evaporated to dryness under reduced pressure and the residue recrystallized from ethanol to give the desired product as yellow crystals having a melting point of 214°-215° C.

Aufarbeitung

  1. customover 30 minutes
  2. extractionextracted with methylene chloride
  3. customThe dried extracts were evaporated to dryness under reduced pressure
  4. customthe residue recrystallized from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-a707d3f725624214a4ace320b4d506a7
Quelldatensatz
uspto-grants-1976_04
Patentnummer
US03952003

Notizen zur Reaktion

Wird geladen…