1-Bromodecane → (4-Decyloxyphenyl)phenyliodonium tosylate

HRID 1638967Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1638967
F[Sb-](F)(F)(F)(F)F.[CH2:8]([O:18][C:19]1[CH:24]=[CH:23][C:22]([I+:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:21][CH:20]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].BrCCCCCCCCCC.C1(OCCCCCCCCCC)C=CC=CC=1.[S:60]([C:72]1[CH:78]=[CH:77][C:75]([CH3:76])=[CH:74][CH:73]=1)([O:63][IH](C1C=CC=CC=1)=O)(=[O:62])=[O:61]>ClCCl.C(O)(=O)C>[S:60]([C:72]1[CH:78]=[CH:77][C:75]([CH3:76])=[CH:74][CH:73]=1)([O-:63])(=[O:62])=[O:61].[CH2:8]([O:18][C:19]1[CH:24]=[CH:23][C:22]([I+:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:21][CH:20]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

Komponenten

7

Edukt 4

HCID 81731-BromodecaneHCID 520713Decyloxybenzene2×HCID 16687828(4-Decyloxyphenyl)phenyliodonium hexafluoroantimonateHCID 178427798HCID 178427798, Verbindung

Produkt 1

HCID 86743519(4-Decyloxyphenyl)phenyliodonium tosylateAusbeute 67,5 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 176Acetic AcidLösungsmittelHCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

The procedure of Example 1 was repeated to prepare (4-decyloxyphenyl)phenyliodonium hexafluoroantimonate. 1-bromodecane was used and the yield of decyl phenyl ether was 98.9%. In accordance with Example 1, 196 grams (0.5 mol) of phenyliodoso tosylate, 117 grams (0.5 mol) of the decyl phenyl ether, 50 ml of acetic acid and 200 ml of dichloromethane were stirred at 40° C. for 2 hours. The reaction mixture was filtered and a solution triturated with ether. The crystallized product was isolated by suction filtration and washed with ether and then dried under vacuum. There was obtained, 205.3 grams (67.5% yield of (4-decyloxyphenyl)phenyliodonium tosylate.

Aufarbeitung

  1. filtrationThe reaction mixture was filtered
  2. customa solution triturated with ether
  3. customThe crystallized product was isolated by suction filtration
  4. washwashed with ether
  5. customdried under vacuum
  6. customThere was obtained

Quellen und Nachweise

ORD-Eintrag
ord-d4316c3d2adf41ca86364c29c40e2dd5
Quelldatensatz
uspto-grants-1989_11
Patentnummer
US04882201

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