Isophthaloyl chloride → N,N'-bis(4-phenoxyphenyl)pyridine-2,6-dicarboxamide

HRID 1648673

Reaktionsgleichung

Reaktionsgleichung von HRID 1648673
[O:1]([C:8]1[CH:14]=[CH:13][C:11]([NH2:12])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N:15]1[C:20]([C:21](Cl)=[O:22])=[CH:19][CH:18]=[CH:17][C:16]=1[C:24](Cl)=[O:25].C(Cl)(=O)[C:28]1[CH:36]=[CH:35][CH:34]=[C:30](C(Cl)=O)[CH:29]=1.[Cl-].[Al+3].[Cl-].[Cl-]>ClCCCl.CN(C=O)C>[O:1]([C:8]1[CH:9]=[CH:10][C:11]([NH:12][C:24]([C:16]2[CH:17]=[CH:18][CH:19]=[C:20]([C:21]([NH:12][C:11]3[CH:13]=[CH:14][C:8]([O:1][C:28]4[CH:29]=[CH:30][CH:34]=[CH:35][CH:36]=4)=[CH:9][CH:10]=3)=[O:22])[N:15]=2)=[O:25])=[CH:13][CH:14]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Komponenten

7

Edukt 4

HCID 7451Isophthaloyl chlorideHCID 8764(4-Aminophenoxy)benzeneHCID 773352,6-Pyridinedicarbonyl dichlorideHCID 6451240Aluminum(III) Chloride

Produkt 1

HCID 1010580N,N'-bis(4-phenoxyphenyl)pyridine-2,6-dicarboxamide

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 111,2-DichloroethaneLösungsmittelHCID 6228DimethylformamideLösungsmittel

Versuchsvorschrift

N,N'-Bis-(4-phenoxyphenyl)-2,6-pyridine dicarboxamide was prepared from p-phenoxyaniline and 2,6-pyridine dicarboxylic acid dichloride. The amide (8.0248 g, 0.016 moles) was polymerized with isophthaloyl chloride (3.2484 g, 0.016) using the procedure of Example 27. The amounts of aluminum chloride, DMF and DCE used were 21.33 g (0.160 moles), 4.71 mL (0.061 mol) and 100 mL, respectively. The off-white fibrous polymer which was obtained had the repeat unit ##STR46##

Aufarbeitung

  1. customThe off-white fibrous polymer which was obtained

Quellen und Nachweise

ORD-Eintrag
ord-51852a99970341b7b554bbcdee9fbc0c
Quelldatensatz
uspto-grants-1995_07
Patentnummer
US05436310

Verknüpfte Notizen

Wird geladen…