[CH2:1]=[CH:2][C:3]([Cl:5])=[CH2:4].[C:6]([O:11][CH3:12])(=[O:10])C(C)=C.C(S)CCCCCCCCCCC.CCCCCCCCCCCCC1C=CC(S(O)(=O)=O)=CC=1.C(N(CCO)CCO)CO.C(C1C=CC=CC=1O)CCCCCCCC.C1OC1.S([O-])([O-])=O.[Na+].[Na+].[OH-].[K+].S(OOS([O-])(=O)=O)([O-])(=O)=O.[K+].[K+].C1C2NC3C(=CC=CC=3)SC=2C=CC=1>O>[CH2:1]=[CH:2][C:3]([Cl:5])=[CH2:4].[C:6]([O:11][CH3:12])(=[O:10])[C:3]([CH3:2])=[CH2:4]
A chloroprene/methyl methacrylate graft copolymer was prepared as follows. A mixture of 80 parts chloroprene, 20 parts methyl methacrylate, and 0.2 parts n-dodecylmercaptan was emulsified with 110 parts water, 5 parts 60% triethanolammonium dodecylbenzene sulfonate, 1 part nonyl phenol condensed with 10 moles of ethylene oxide, 0.3 parts sodium sulfite, and 0.24 parts potassium hydroxide. Polymerization was initiated at 15° C. by addition of potassium persulfate and the temperature was maintained until the specific gravity of the emulsion reached 1.060 B which represented a conversion of 75%. The temperature of the emulsion was then raised to 48° C. and polymerization continued until no further specific gravity increase was observed. The conversion was greater than 99% and a shortstopping agent, phenothiazine, was added. The solids content of the emulsion was 47.0%.
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