Water → HCID 12770097, Verbindung

HRID 1659445

Reaktionsgleichung

Reaktionsgleichung von HRID 1659445
CS[S:3][CH3:4].[CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH:6]=1.[OH2:11].[C:12](#[N:14])[CH3:13]>F[B-](F)(F)F.C([N+](CCCC)(CCCC)CCCC)CCC.[Pt]>[C:12]([NH:14][CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH:6]1[S:3][CH3:4])(=[O:11])[CH3:13]

Komponenten

7

Edukt 4

HCID 962WaterHCID 6342AcetonitrileHCID 8079CyclohexeneHCID 12232Dimethyl Disulfide

Produkt 1

HCID 12770097HCID 12770097, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23939PlatinumKatalysatorHCID 67932Tetrabutylammonium TetrafluoroborateKatalysator

Versuchsvorschrift

A mixture of dimethyldisulphide (96 mg) in acetonitrile containing cyclohexene (405 mg) was placed in a conventional H-type electrolytic cell. The cell was provided with a number 4 sintered glass frit as divider and with 1 sq. cm. platinum mesh cathode and anode. The potential measurement was made with respect to a Ag/Ag+ (0.01 M) reference electrode. Tetra-n-butyl ammonium fluoroborate (0.1 M) was added as electrolyte. A constant potential of 1.20 volts was maintained at the anode with a potentiostat until 2 coulomb equivalents of charge per mole of disulphide had been passed. Water was then added to the anolyte and the aqueous phase extracted with diethyl ether to yield 116 mg of 2-acetamido 1-methylthio cyclohexane. Mass Spec. m/e 187 (parent ion). I.R. 3290 & 1650 cm-1.

Aufarbeitung

  1. customThe cell was provided with a number 4 sintered glass frit as divider and with 1 sq. cm
  2. temperatureA constant potential of 1.20 volts was maintained at the anode with a potentiostat until 2 coulomb equivalents
  3. extractionthe aqueous phase extracted with diethyl ether

Quellen und Nachweise

ORD-Eintrag
ord-cca45905f75849ea9cac28a2fe69eaf8
Quelldatensatz
uspto-grants-1981_12
Patentnummer
US04304642

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