2-Chloroethyl chloroformate → HCID 20524951, Verbindung

HRID 1702757

Reaktionsgleichung

Reaktionsgleichung von HRID 1702757
[O:1]([CH2:8][CH:9]([OH:12])[CH2:10][Cl:11])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl[C:14]([O:16][CH2:17][CH2:18][Cl:19])=[O:15]>>[C:14](=[O:15])([O:12][CH:9]([CH2:8][O:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[CH2:10][Cl:11])[O:16][CH2:17][CH2:18][Cl:19]

Komponenten

3

Edukt 2

HCID 123052-Chloroethyl chloroformateHCID 943001-Chloro-3-phenoxy-2-propanol

Produkt 1

HCID 20524951HCID 20524951, Verbindung

Versuchsvorschrift

By reacting 3-phenoxy-1-chloro-2-propanol with 2-chloroethyl chloroformate according to conventional chloroformate ester reaction procedures, 2-chloroethyl 3-phenoxy-1-chloro-2-propyl carbonate is obtained. When the latter compound is heated in the presence of a phosphonium or ammonium salt catalyst as shown in the foregoing examples, phenyl glycidyl ether is produced as the principal epoxide product.

Quellen und Nachweise

ORD-Eintrag
ord-ee227660f37a44498bf640fc72e565fe
Quelldatensatz
uspto-grants-1982_09
Patentnummer
US04349482

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