Reaktionsgleichung
[C:1]([O:9][CH3:10])(=[O:8])/[CH:2]=[CH:3]/[C:4]([O:6][CH3:7])=[O:5].[CH:11]([O:13][CH2:14][CH2:15][CH2:16]CO)=[CH2:12]>C([O-])(=O)C.[Zn+2].C([O-])(=O)C.CC(C1C(O)=C(C(C)(C)C)C=C(CCC(OCC(COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)(COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)COC(CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)=O)C=1)(C)C.CO>[C:1]([O:9][CH2:10][CH2:16][CH2:15][CH2:14][O:13][CH:11]=[CH2:12])(=[O:8])/[CH:2]=[CH:3]/[C:4]([O:6][CH2:7][CH2:16][CH2:15][CH2:14][O:13][CH:11]=[CH2:12])=[O:5]Komponenten
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 3
Versuchsvorschrift
Into a 1 L-volume flask equipped with a distillation unit, 144 g of dimethyl fumarate, 279 g of hydroxybutyl vinyl ether, 0.2 g of zinc acetate and 0.3 g of IRGANOX 1010 as a polymerization inhibitor were charged. The mixture was heated to 140° C. in a nitrogen atmosphere and methanol generated as a by-product was distilled off. When methanol reached 70% of the theoretical amount, the pressure inside of the reaction system was gradually reduced to accelerate the distillation of methanol, and by finally reducing the pressure to about 400 Pa, the theoretical amount of methanol and the residual hydroxybutyl vinyl ether were completely distilled off. The reaction solution was cooled to a room temperature and then 297 g of bis(4-vinyloxybutyl) fumarate was obtained.
Aufarbeitung
- additionwere charged
- distillationwas distilled off
- distillationthe distillation of methanol
- distillationthe theoretical amount of methanol and the residual hydroxybutyl vinyl ether were completely distilled off
Quellen und Nachweise
- ORD-Eintrag
- ord-25717d553514433eb13306a17ff7ccc7
- Quelldatensatz
- uspto-grants-2006_05
- Patentnummer
- US07038076B2
Verknüpfte Notizen
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