Dinitrofluorobenzene → HCID 4922992, Verbindung

HRID 1856607Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1856607
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1F)([O-:3])=[O:2].CN1CCCC1=O.[CH2:21]([NH:24][CH2:25][CH:26]=[CH2:27])[CH:22]=[CH2:23].C(=O)([O-])[O-].[K+].[K+]>O>[CH2:21]([N:24]([CH2:25][CH:26]=[CH2:27])[C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])[CH:22]=[CH2:23]

Komponenten

6

Edukt 4

HCID 6264DinitrofluorobenzeneHCID 11430Potassium CarbonateHCID 13387N-methyl-2-pyrrolidoneHCID 31279Diallylamine

Produkt 1

HCID 4922992HCID 4922992, VerbindungAusbeute 111 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

A mixture of 2,4-dinitrofluorobenzene (9.3 g), N-methylpyrrolidinone (NMP, 50 mL), diallylamine (5.82 g) and potassium carbonate (6.9 g) was stirred at ambient temperature for 1 h. The mixture was poured into water and extracted with ethyl ether. The extract was washed twice with water, once with saturated brine solution, and dried over magnesium sulfate. Concentration of the extract gave N,N-diallyl-2,4-dinitrobenzenamine as a yellow oil (14.6 g).

Aufarbeitung

  1. extractionextracted with ethyl ether
  2. washThe extract was washed twice with water, once with saturated brine solution
  3. dry with materialdried over magnesium sulfate

Quellen und Nachweise

ORD-Eintrag
ord-859da6a323f94900a5fb7486335f97d3
Quelldatensatz
uspto-grants-2000_11
Patentnummer
US06143380

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