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Carbon Dioxide → Terephthalic Acid

HRID 1979101
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 1979101
C(=O)(O)[O-].[Na+].[C:6]1(=[O:19])[O:16]CC[O:13][C:11](=[O:12])[C:10]2[CH:17]=[CH:18][C:7]1=[CH:8][CH:9]=2.C(=O)=O>O>[C:6]([OH:19])(=[O:16])[C:7]1[CH:18]=[CH:17][C:10]([C:11]([OH:13])=[O:12])=[CH:9][CH:8]=1
KomponentenReaktionsbedingungenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

5

Edukt 3

HCID 280Carbon DioxideHCID 516892Sodium BicarbonateHCID 15066111Ethylene terephthalate, cyclic-(1:1)-

Produkt 1

HCID 7489Terephthalic Acid

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Reaktionsbedingungen

Temperatur
200 °C

Versuchsvorschrift

In a heated autoclave, provided with a mixer and filled partially with water, cut poly/ethyleneterephtalate/ wastes in a form of scraps of foil and pieces of industrial shapes were placed in the amount of 1000 g together with a solution of 875 g of sodium bicarbonate (NaHCO3) in 10 liters of water, and then a content of the reactor was heated up to 200° C. and the temperature was kept till the digestion of poly/ethylene terephtalate/ was completed and the formation of carbon dioxide was stopped. Then the autoclave was relieved and carbon dioxide and water excess were separated, then a resulted solution was filtered hot through a filter with active carbon. The filtrate was neutralised with hydrochloric acid and a precipitate of terephtalic acid was separated from a reaction solution using a centrifuge. The resulted product was washed with a distilled water and crystallised from water, giving 864 g of terephtalic acid. At the same time ethylene glycol was separated from the neutralised filtrate using extraction with diethylcarbonate, obtaining 322,6 g of ethylene glycol.

Aufarbeitung

  1. customIn a heated autoclave, provided with a mixer and
  2. customcarbon dioxide and water excess were separated
  3. filtrationa resulted solution was filtered hot through
  4. filtrationa filter with active carbon
  5. customa precipitate of terephtalic acid was separated from a reaction solution
  6. washThe resulted product was washed with a distilled water
  7. customcrystallised from water

Quellen und Nachweise

ORD-Eintrag
ord-08165c85cbfe4362af6acdaadf2df849
Quelldatensatz
uspto-grants-2001_05
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US06239310B1

Notizen zur Reaktion

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