Water → [3-(2-Furyl)phenyl]methanol

HRID 2254445Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2254445
[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[CH:7]=[C:8]([CH:14]=[CH:15][CH:16]=1)[C:9](OCC)=[O:10].[H-].[Al+3].[Li+].[H-].[H-].[H-].O>C(OCC)C>[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[CH:7]=[C:8]([CH:14]=[CH:15][CH:16]=1)[CH2:9][OH:10]

Komponenten

5

Edukt 3

HCID 962WaterHCID 19744763Ethyl 3-(furan-2-yl)benzoateHCID 21226445Aluminium lithium hydride

Produkt 1

HCID 11116545[3-(2-Furyl)phenyl]methanolAusbeute 83 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel2×

Versuchsvorschrift

Ethyl 3-(2-furyl)benzoate [J. Chem. Soc., (B), 1971, 2305 was dissolved in 5 ml of anhydrous ethyl ether. With stirring under ice cooling, 23 mg of lithium aluminium hydride was added The mixture was stirred for 40 minutes. After the reaction, water and ethyl ether were added to extract the reaction mixture The extract was worked up in a customary manner to give 170 mg (yield 83%) of 3-(2-furyl)benzyl alcohol

Aufarbeitung

  1. stirringwas stirred for 40 minutes
  2. additionwere added
  3. extractionto extract the reaction mixture The extract

Quellen und Nachweise

ORD-Eintrag
ord-04c96a60e1bb477194670d995865208b
Quelldatensatz
uspto-grants-1993_08
Patentnummer
US05234946

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