Dimethylformamide → N-butyl-N-(2-methylprop-2-eneyl)aniline

HRID 2258380

Reaktionsgleichung

Reaktionsgleichung von HRID 2258380
[CH2:1]([NH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].C(=O)([O-])[O-].[K+].[K+].Cl[CH2:19][C:20]([CH3:22])=[CH2:21].CN(C=O)C>C1(C)C=CC=CC=1>[CH2:1]([N:5]([CH2:21][C:20]([CH3:22])=[CH2:19])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4]

Komponenten

6

Edukt 4

HCID 6228DimethylformamideHCID 112413-Chloro-2-methyl-1-propeneHCID 11430Potassium CarbonateHCID 14310N-Butylaniline

Produkt 1

HCID 54010992N-butyl-N-(2-methylprop-2-eneyl)aniline

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Reaktionsbedingungen

Temperatur
90 °C

Versuchsvorschrift

A mixture of N-butylaniline (12.35 parts), anhydrous potassium carbonate (17.1 parts), 3-chloro-2-methylpropene (11.24 parts) and DMF (20 parts) was stirred at 90° C. for 8 hours. The cooled mixture was poured into toluene, washed with water (×2), 1N hydrochloric acid (30 parts) and water (×2). The dried organic phase was evaporated to leave N-butyl-N-(2-methylprop-2-eneyl)aniline (14.3 parts).

Aufarbeitung

  1. washwashed with water (×2), 1N hydrochloric acid (30 parts) and water (×2)
  2. customThe dried organic phase was evaporated

Quellen und Nachweise

ORD-Eintrag
ord-fbce872db8c94b7daf813f5029f98905
Quelldatensatz
uspto-grants-1997_08
Patentnummer
US05660598

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