Reaktionsgleichung
[C:1]1(=[O:6])[O:5][CH2:4][CH2:3][O:2]1>O.O.O.[O-][Sn]([O-])=O.[Na+].[Na+]>[C:1]1(=[O:6])[O:5][CH2:4][CH2:3][O:2]1.[C:1](=[O:5])=[O:2]Komponenten
4
Edukt 1
Produkt 2
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 175 °C
Versuchsvorschrift
A 10:1 mole ratio of ethylene carbonate to polyester polyol (poly(caprolactone) diol, MW=530) is heated with stirring under a nitrogen atmosphere for 4 hours at 175° C. using 0.5 percent sodium stannate trihydrate as catalyst to give 97.9 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 19.2 percent carbon dioxide. The catalyst is removed as in Example 1.
Quellen und Nachweise
- ORD-Eintrag
- ord-83e27cce764c40d789da328866ec9e7a
- Quelldatensatz
- uspto-grants-1987_11
- Patentnummer
- US04709069
Verknüpfte Notizen
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