Hydrochloric Acid → Tri-n-decylcarbinol

HRID 2583

Reaktionsgleichung

Reaktionsgleichung von HRID 2583
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Mg].C(=O)([O:17][CH2:18][CH3:19])OCC.Cl>C(OCC)C>[CH2:2]([C:18]([CH2:19][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[OH:17])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Komponenten

6

Edukt 4

HCID 313Hydrochloric AcidHCID 7766Diethyl CarbonateHCID 81731-BromodecaneHCID 5462224Magnesium

Produkt 1

HCID 19690419Tri-n-decylcarbinol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel2×

Reaktionsbedingungen

Temperatur
30 °C

Versuchsvorschrift

Three moles of 1-bromodecane was slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether was slowly added to the mixture. After stirring for one hour at 30° C., the mixture was slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer was dried with magnesium sulfate and the ethyl ether evaporated off to give tri-n-decylcarbinol.

Aufarbeitung

  1. dry with materialThe organic layer was dried with magnesium sulfate
  2. customthe ethyl ether evaporated off

Quellen und Nachweise

ORD-Eintrag
ord-5831ca84c85c45188e821732a2150987
Quelldatensatz
uspto-grants-1998_03
Patentnummer
US05728907

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