Water → Perfluorodecenyloxybenzenesulfonamide

HRID 261126

Reaktionsgleichung

Reaktionsgleichung von HRID 261126
C(O)(=O)CCCCCCCCCCCCCCCCCCCCC.[NH2:25]CCNCCNCCN.O.C(N)(=O)CCCCCCCCCCCCCCCCCCCCC.NCCNCCNCCN.[F:70][C:71]1[C:72]([O:84][C:85]([F:113])=[C:86]([F:112])[C:87]([F:111])([F:110])[C:88]([F:109])([F:108])[C:89]([F:107])([F:106])[C:90]([F:105])([F:104])[C:91]([F:103])([F:102])[C:92]([F:101])([F:100])[C:93]([F:99])([F:98])[C:94]([F:97])([F:96])[F:95])=[C:73]([S:80](Cl)(=[O:82])=[O:81])[C:74]([F:79])=[C:75]([F:78])[C:76]=1[F:77].C(=O)([O-])[O-].[Na+].[Na+]>ClC(Cl)=C(Cl)Cl>[F:70][C:71]1[C:72]([O:84][C:85]([F:113])=[C:86]([F:112])[C:87]([F:111])([F:110])[C:88]([F:109])([F:108])[C:89]([F:107])([F:106])[C:90]([F:105])([F:104])[C:91]([F:103])([F:102])[C:92]([F:101])([F:100])[C:93]([F:99])([F:98])[C:94]([F:97])([F:96])[F:95])=[C:73]([S:80]([NH2:25])(=[O:82])=[O:81])[C:74]([F:79])=[C:75]([F:78])[C:76]=1[F:77]

Komponenten

8

Edukt 6

HCID 962WaterHCID 5565TriethylenetetramineHCID 8215Docosanoic AcidHCID 10340Sodium CarbonateHCID 86736606Perfluorodecenyloxybenzene sulfonyl chlorideHCID 131711591Triethylenetetramine monobehenamide

Produkt 1

HCID 86736605Perfluorodecenyloxybenzenesulfonamide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 31373TetrachloroethyleneLösungsmittel

Versuchsvorschrift

Behenic acid (98.4 g., 0.3 mol) and triethylenetetramine (43.8 g, 0.3 mol) was reacted at 158°-161° C. until 0.3 mol of water had been evolved (25 minutes) 47.4 g (0.1 mole) of the resulting triethylenetetramine monobehenamide was dissolved in 50 ml. of perchloroethylene. To the resulting solution was added a mixture of 80.0 g (0.12 mol) of perfluorodecenyloxybenzenesulfonyl chloride and 7.0 g of sodium carbonate over a 20 minute period, while holding the temperature at 95°-120° C. After one hour at 90°-120° C., the mixture was worked up as in the preceding example to yield the product, 1.2 perfluorodecenyloxybenzenesulfonamide of triethylene tetramine monobehenamide, a tan, hard, waxy, solid with good oil, water and soil repellancy.

Aufarbeitung

  1. dissolutionwas dissolved in 50 ml
  2. additionTo the resulting solution was added
  3. customat 95°-120° C

Quellen und Nachweise

ORD-Eintrag
ord-58acc04bd19242fdb5e4c6936f641695
Quelldatensatz
uspto-grants-1979_08
Patentnummer
US04163754

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