Acetic Acid → HCID 53908697, Verbindung

HRID 263619

Reaktionsgleichung

Reaktionsgleichung von HRID 263619
[CH3:1][CH:2]1[CH2:10][C:9]2[C:4](=[CH:5][C:6]([N+:11]([O-:13])=[O:12])=[CH:7][CH:8]=2)[C:3]1=[O:14].[CH3:15][O:16][C:17]1[CH:25]=C2C(CC(C)C2=O)=CC=1.C([OH:30])C.C(O)(=O)C>O>[OH:14][C:3]1([CH2:25][C:17]([O:16][CH3:15])=[O:30])[C:4]2[C:9](=[CH:8][CH:7]=[C:6]([N+:11]([O-:13])=[O:12])[CH:5]=2)[CH:10]=[C:2]1[CH3:1]

Komponenten

6

Edukt 4

HCID 176Acetic AcidHCID 702EthanolHCID 2311786-Methoxy-2-methyl-2,3-dihydro-1H-inden-1-oneHCID 21840586HCID 21840586, Verbindung

Produkt 1

HCID 53908697HCID 53908697, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

The procedure of Example 1C is followed using 2-methyl-6-nitro indanone in equivalent quantities in place of 6-methoxy-2-methyl-indanone used therein. After the mixture is condensed, 30 ml. of ethanol and 50 ml. of acetic acid are added. The mixture is then poured into 700 ml. of water. Extraction with ether gives methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate.

Aufarbeitung

  1. customcondensed, 30 ml
  2. additionThe mixture is then poured into 700 ml
  3. extractionExtraction with ether

Quellen und Nachweise

ORD-Eintrag
ord-492f7d423e534647afa22075b85263ca
Quelldatensatz
uspto-grants-1997_07
Patentnummer
US05643959

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