Butanal → Butanal

HRID 268194

Reaktionsgleichung

Reaktionsgleichung von HRID 268194
N[C:2]1([O:8]O)[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[CH:10](=[O:14])[CH2:11][CH2:12][CH3:13].C(O)(=O)C.N>CO>[C:2]1(=[O:8])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[CH:10](=[O:14])[CH2:11][CH2:12][CH3:13]

Komponenten

6

Edukt 3

HCID 261ButanalHCID 12432Ammonia acetateHCID 193800581-Aminocyclohexyl hydroperoxide

Produkt 2

HCID 261ButanalHCID 7967Cyclohexanone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

1-Aminocyclohexyl hydroperoxide (13.1 g.), butyraldehyde (7.2 g.), methanol (25 cc.) and ammonia acetate (1.0 g.) were mixed and stored at 0°C overnight. Working up as in Example 39 gave cyclohexanone and butyraldehyde, and a product (8.4 g.), b.p. 89°/0.3 mm. (peroxide equivalent, 204; pechloric acid equivalent, 206; which was identified as ##SPC37##

Quellen und Nachweise

ORD-Eintrag
ord-d71560725e124bf9937c2ce881b6cce1
Quelldatensatz
uspto-grants-1976_03
Patentnummer
US03947406

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