Formic Acid → 95903-63-2

HRID 34326Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 34326
[CH3:1][O:2][C:3]1[C:12]([C:13]([O:15][CH3:16])=[O:14])=[CH:11][C:10]2[C:5](=[CH:6][C:7]([S:17]CC3C=CC(OC)=CC=3)=[CH:8][CH:9]=2)[N:4]=1.C(O)=O.O.S>C(Cl)Cl>[SH:17][C:7]1[CH:6]=[C:5]2[C:10]([CH:11]=[C:12]([C:13]([O:15][CH3:16])=[O:14])[C:3]([O:2][CH3:1])=[N:4]2)=[CH:9][CH:8]=1

Komponenten

6

Edukt 4

HCID 284Formic AcidHCID 402Hydrogen SulfideHCID 962WaterHCID 13744932HCID 13744932, Verbindung

Produkt 1

HCID 13604047795903-63-2

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

A mixture of the ester from Step 4 (2.77 g), 90% formic acid (70 ml) and mercuric acetate (7.17 g) was stirred under an argon atmosphere at ambient temperature for 3 hours. The reaction mixture was poured into a mixture of water (350 ml) and CH2Cl2 (700 ml) and H2S gas was passed through the vigorously stirred mixture for 5 minutes. The organic phase was separated, filtered through celite, washed with water, dried (MgSO4) and reduced to dryness to provide the title compound, m.p. 103°-105°.

Aufarbeitung

  1. waitwas passed through the vigorously stirred mixture for 5 minutes
  2. customThe organic phase was separated
  3. filtrationfiltered through celite
  4. washwashed with water
  5. dry with materialdried (MgSO4)

Quellen und Nachweise

ORD-Eintrag
ord-0a64db695d6e46b6935c174f213cc5ca
Quelldatensatz
uspto-grants-1988_08
Patentnummer
US04761425

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