Formic Acid → HCID 69858079, Verbindung

HRID 343732

Reaktionsgleichung

Reaktionsgleichung von HRID 343732
[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15].C(O)=O.[Cu:20].C(O)=O>CO>[Cu:20].[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15]

Komponenten

5

Edukt 3

HCID 284Formic AcidHCID 143572,6-Naphthalenedicarboxylic acidHCID 44152240Formic acid, copper salt

Produkt 1

HCID 69858079HCID 69858079, VerbindungAusbeute 67,6 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel2×

Versuchsvorschrift

0.40 g of 2,6-naphthalene dicarboxylic acid was dissolved under heating in a mixture solvent of 4000 cm3 of methanol and 5 cm3 of formic acid. After this solution was cooled to the normal temperature, into this solution under stirring, a further solution in which 3.00 g of formic acid copper was dissolved in 100 cm3 of methanol was dripped and then this was kept still for a few days. Thereafter, the precipitation product was suction-filtered and dried for 110° C./4 hours, whereby 0.35 g of 2,6-naphthalene dicarboxylic acid copper was obtained.

Aufarbeitung

  1. temperatureAfter this solution was cooled to the normal temperature, into this solution
  2. waitthis was kept still for a few days
  3. filtrationThereafter, the precipitation product was suction-filtered
  4. customdried for 110° C./4 hours

Quellen und Nachweise

ORD-Eintrag
ord-c4bbc6cb1fc74cb0907db7ff81c62b12
Quelldatensatz
uspto-grants-1999_01
Patentnummer
US05862796

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