Benzene → Butylbenzene

HRID 345611

Reaktionsgleichung

Reaktionsgleichung von HRID 345611
Cl[CH2:2][CH2:3][CH2:4][CH3:5].NC(N)=O.S(=O)(=O)(O)O.NC(N)=O.S(=O)(=O)(O)O.[CH:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>>[CH2:2]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)[CH2:3][CH2:4][CH3:5]

Komponenten

6

Edukt 5

HCID 241BenzeneHCID 1118Sulfuric AcidHCID 1176UreaHCID 8005Butyl ChlorideHCID 159909Urea sulfate2×

Produkt 1

HCID 7705Butylbenzene

Versuchsvorschrift

Normal-butylbenzene is prepared by heating equal molar amounts of 1-chlorobutane and benzene in a molten urea-sulfuric acid component containing 42.6 weight percent urea and 75.4 weight percent sulfuric acid having a urea/sulfuric acid molar ratio of 1.2 at a temperature of 140° F. and a pressure of 100 psig. for a period of 10 minutes. The n-butylbenzene product is recovered by cooling the reaction mixture to solidify the urea-sulfuric acid component melt and extracting the resulting mixture with toluene. The n-butylbenzene product is removed from the toluene solvent by distilling the solvent, and the urea-sulfuric acid component is re-melted and recycled to the process.

Aufarbeitung

  1. customThe n-butylbenzene product is recovered
  2. temperatureby cooling the reaction mixture
  3. extractionextracting the resulting mixture with toluene
  4. customThe n-butylbenzene product is removed from the toluene solvent
  5. distillationby distilling the solvent

Quellen und Nachweise

ORD-Eintrag
ord-faf367446e454c518cfbcf28d9354641
Quelldatensatz
uspto-grants-1991_10
Patentnummer
US05057584

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