Hexane → cis-Stilbene

HRID 351960

Reaktionsgleichung

Reaktionsgleichung von HRID 351960
[C:1]1([C:7]#[C:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CCCCCC>C1COCC1>[C:1]1(/[CH:7]=[CH:8]\[C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Komponenten

4

Edukt 2

HCID 8058HexaneHCID 10390Diphenylacetylene

Produkt 1

HCID 5356785cis-Stilbene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

In the foregoing epititanations of diphenylacetylene conducted in THF or hexane, parallel epititanations were conducted in the same manner but the hydrolytic workup in each case was performed with 3N DCl in D2O. In these experiments the cis-stilbene isolated was >98% dideuteriated at the vinylic carbon atoms (12).

Quellen und Nachweise

ORD-Eintrag
ord-9507fa7fcc184888bfcbd3570c598bd7
Quelldatensatz
uspto-grants-2004_06
Patentnummer
US06743872B1

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