Styrene → Benzene, ethenyl-, polymer with 1,3-butadiene

HRID 353650

Reaktionsgleichung

Reaktionsgleichung von HRID 353650
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:9]=[CH:10][CH:11]=[CH2:12].CN(CCN(C)C)C.[Li]CCCC>>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:9]=[CH:10][CH:11]=[CH2:12]

Komponenten

5

Edukt 4

HCID 7501StyreneHCID 78451,3-ButadieneHCID 8037N,N,N',N'-TetramethylethylenediamineHCID 178418339Butyllithium

Produkt 1

HCID 62697Benzene, ethenyl-, polymer with 1,3-butadiene

Versuchsvorschrift

In this example, a 1/11/88 PES/styrene/1,3-butadiene terpolymer was prepared using the procedure described in Example 34 except that the ratio of PES to styrene and to 1,3-butadiene was changed to 1:11:80 and the molar ratio of TMEDA to n-BuLi was also changed to 1:1. GC analysis of residual monomer with respect to polymerization time indicated that PES was randomly distributed along the polymer chain. The resulting terpolymer had a Tg at −42° C. and was determined to a have a ML-4 of 47.

Aufarbeitung

  1. customGC analysis of residual monomer with respect to polymerization time
  2. customat −42° C.

Quellen und Nachweise

ORD-Eintrag
ord-53e0851c347d4509bc52251a0e84c4f5
Quelldatensatz
uspto-grants-2004_06
Patentnummer
US06753447B2

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