Phloroglucinol → Bisphenol P

HRID 354523

Reaktionsgleichung

Reaktionsgleichung von HRID 354523
[C:1]1([CH:9]=[C:7]([OH:8])[CH:6]=[C:4](O)[CH:3]=1)O.CC(C1C=CC(O)=CC=1)([CH2:22][C:23]([CH3:32])([C:25]1[CH:30]=[CH:29][C:28]([OH:31])=[CH:27][CH:26]=1)[CH3:24])CC(C1C=CC(O)=CC=1)C.OC1[CH:46]=[CH:45][C:44]([C:47]2[CH:52]=C(C3C=CC(O)=CC=3)C=C(C3C=CC(O)=CC=3)[CH:48]=2)=[CH:43][CH:42]=1.OC1C=CC(C(C2C=CC(O)=CC=2)(C2C=CC(O)=CC=2)C)=CC=1.OC1C=CC(C(C2C=CC(O)=CC=2)(C2C=CC(O)=CC=2)C2C=CC=CC=2)=CC=1.OC1C=C(O)C=CC=1C(O)=O.OC1C=CC(C(C2C=CC(O)=CC=2O)(C)C)=CC=1>>[OH:31][C:28]1[CH:27]=[CH:26][C:25]([C:23]([C:22]2[CH:46]=[CH:45][C:44]([C:47]([C:3]3[CH:4]=[CH:6][C:7]([OH:8])=[CH:9][CH:1]=3)([CH3:52])[CH3:48])=[CH:43][CH:42]=2)([CH3:32])[CH3:24])=[CH:30][CH:29]=1

Komponenten

8

Edukt 7

HCID 359PhloroglucinolHCID 14912,4-Dihydroxybenzoic AcidHCID 931181,1,1-Tris(4-hydroxyphenyl)ethaneHCID 3481481,3,5-Tris(4-hydroxyphenyl)benzeneHCID 17820215Tri-(4-hydroxyphenyl)-phenyl methaneHCID 218855202-(4-Hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propaneHCID 218944334,6-Dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane

Produkt 1

HCID 630355Bisphenol P

Versuchsvorschrift

The polycarbonates may, of course, be branched by incorporating small quantities of polyhydroxyl compounds, e.g. 0.05 to 2.0 mols percent (based on the quantity of bisphenols). Polycarbonates of this kind have been described, e.g. in German Offenlegungsschriften No. 1,570,533; 2,116,974 and 2,113,347, in British Patents No. 885,442 and 1,079,821 and in U.S. Pat. No. 3,544,514. The following are some of the polyhydroxyl compounds which are suitable for this purpose: Phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptene-(2), 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4-hydroxyphenyl)-benzene, 1,1,1-tri-(4-hydroxyphenyl)-ethane, tri-(4-hydroxyphenyl)-phenyl-methane, 2,2-bis-[4,4-(4,4'-dihydroxydiphenyl)-cyclohexyl]-propane, 2,4-bis-(4-hydroxyphenyl-4-isopropyl)-phenol,2,6-bis-(2'-hydroxy-5'-methyl-benzyl)-4-methylphenol, 2,4-dihydroxybenzoic acid, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane and 1,4-bis-(4',40"-dihydroxytriphenyl-methyl)-benzene.

Quellen und Nachweise

ORD-Eintrag
ord-6ada6bb5c4e344879e79e1c331e424be
Quelldatensatz
uspto-grants-1983_03
Patentnummer
USRE031165

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