Methane → 1,1,1-Trichloro-4-methylpent-3-en-2-ol

HRID 370558Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 370558
[Cl:1][C:2]([Cl:10])([Cl:9])[CH:3]([OH:8])[CH2:4][C:5]([CH3:7])=[CH2:6].C>CCOCC>[Cl:1][C:2]([Cl:10])([Cl:9])[CH:3]([OH:8])[CH:4]=[C:5]([CH3:7])[CH3:6]

Komponenten

4

Edukt 2

HCID 297MethaneHCID 913911,1,1-Trichloro-4-methylpent-4-en-2-ol2×

Produkt 1

HCID 30144241,1,1-Trichloro-4-methylpent-3-en-2-olAusbeute 59,2 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

1,1,1-Trichloro-4-methyl-4-penten-2-ol (74 g, 0.36 mole) was heated at 140°-150° for 18 hours. After cooling, the alcohol was diluted with ether, and the ethereal solution was treated with activated charcoal. The ether was removed by evaporation to afford crystalline 1,1,1-trichloro-4-methyl-3-penten-2-ol (43.4 g, 59% yield) after recrystallization from petroleum ether.

Aufarbeitung

  1. temperatureAfter cooling
  2. customThe ether was removed by evaporation

Quellen und Nachweise

ORD-Eintrag
ord-8423b11ddcc24eb79bc56c86467346b6
Quelldatensatz
uspto-grants-1985_07
Patentnummer
US04526987

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