Acetic Acid → Propionaldehyde 3-nitrophenylhydrazone

HRID 401256

Reaktionsgleichung

Reaktionsgleichung von HRID 401256
[OH-].[Na+].Cl.[N+:4]([C:7]1[CH:8]=[C:9]([NH:13][NH2:14])[CH:10]=[CH:11][CH:12]=1)([O-:6])=[O:5].C(O)(=O)C.[CH:19](=O)[CH2:20][CH3:21]>C(O)C>[N+:4]([C:7]1[CH:8]=[C:9]([NH:13][N:14]=[CH:19][CH2:20][CH3:21])[CH:10]=[CH:11][CH:12]=1)([O-:6])=[O:5]

Komponenten

6

Edukt 4

HCID 176Acetic AcidHCID 527PropanalHCID 14798Sodium HydroxideHCID 54642853-Nitrophenylhydrazinium(1+) chloride

Produkt 1

HCID 66675029Propionaldehyde 3-nitrophenylhydrazone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

Sodium hydroxide solution (10%, 15 mL) was added slowly to a stirred suspension of (3-nitro-phenyl)-hydrazine hydrochloride salt (B-4-a) (1.89 g, 10 mmol) in ethanol (20 mL) until pH 6. Acetic acid (5 mL) was added to the mixture followed by propionaldehyde (0.7 g, 12 mmol). After stifling for 3 h at room temperature, the mixture was poured into ice-water and the resulting precipitate was isolated via filtration, washed with water and dried in air to obtain N-(3-nitro-phenyl)-N′-propylidene-hydrazine, which was used directly in the next step.

Aufarbeitung

  1. customthe resulting precipitate was isolated via filtration
  2. washwashed with water
  3. customdried in air

Quellen und Nachweise

ORD-Eintrag
ord-bee0786b6d764428bc79846dbc60d2ec
Quelldatensatz
uspto-grants-2014_06
Patentnummer
US08741925B2

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