Benzoyl Peroxide → Methyl 2-(bromomethyl)-3-nitrobenzoate

HRID 420613

Reaktionsgleichung

Reaktionsgleichung von HRID 420613
[CH3:1][O:2][C:3](=[O:14])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-:12])=[O:11])[C:5]=1[CH3:13].[Br:15]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.C1(=O)NC(=O)CC1>C(Cl)(Cl)(Cl)Cl>[CH3:1][O:2][C:3](=[O:14])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-:12])=[O:11])[C:5]=1[CH2:13][Br:15]

Komponenten

6

Edukt 4

HCID 7187Benzoyl PeroxideHCID 11439SuccinimideHCID 67184N-bromobutanimideHCID 601165Methyl 2-methyl-3-nitrobenzoate

Produkt 1

HCID 1487795Methyl 2-(bromomethyl)-3-nitrobenzoate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 5943Carbon TetrachlorideLösungsmittel

Versuchsvorschrift

25.55 g (130.9 mmol) of 2-methyl-3-nitrobenzoic acid methyl ester is added to 300 ml of carbon tetrachloride, and mixed with 25.6 g (141.7 mmol) of N-bromosuccinimide and 62.8 mg of benzoyl peroxide. After seven days of refluxing, the succinimide is suctioned off after cooling, and then the filtrate is spun in until a dry state is reached. The desired compound that is incorporated in crude form into the next stage remains.

Aufarbeitung

  1. temperatureAfter seven days of refluxing
  2. temperatureafter cooling

Quellen und Nachweise

ORD-Eintrag
ord-bac3f96a75ac43479751c769eee1363d
Quelldatensatz
uspto-grants-2012_01
Patentnummer
US08097627B2

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