Potassium Carbonate → N,N-diallyl-6-nitro-1,3-benzenediamine

HRID 428799

Reaktionsgleichung

Reaktionsgleichung von HRID 428799
F[C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][C:8]=1[N+:9]([O-:11])=[O:10])[NH2:5].CN1CCCC1=O.[CH2:19]([NH:22][CH2:23][CH:24]=[CH2:25])[CH:20]=[CH2:21].C(=O)([O-])[O-].[K+].[K+]>O>[CH2:19]([N:22]([CH2:23][CH:24]=[CH2:25])[C:2]1[C:8]([N+:9]([O-:11])=[O:10])=[CH:7][CH:6]=[C:4]([NH2:5])[CH:3]=1)[CH:20]=[CH2:21]

Komponenten

6

Edukt 4

HCID 11430Potassium CarbonateHCID 13387N-methyl-2-pyrrolidoneHCID 31279DiallylamineHCID 754013-Fluoro-4-nitroaniline

Produkt 1

HCID 22251449N,N-diallyl-6-nitro-1,3-benzenediamineAusbeute 98,6 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
120 °C

Versuchsvorschrift

A mixture of 3-fluoro-4-nitroaniline (1.56 g, 10 mmol), 1-methylpyrolidinone (10 mL), diallylamine (1.94 g, 20 mmol) and potassium carbonate (1.38 g, 10 mmol) was heated to 115-125 ° C. for 9.5 h. The mixture was diluted with water, and extracted with ethyl ether. The combined extracts were washed with water, washed with saturated brine solution, and dried over magnesium sulfate. The extract was concentrated to give N,N-diallyl-6-nitro-1,3-benzenediamine as an orange oil (2.3 g).

Aufarbeitung

  1. extractionextracted with ethyl ether
  2. washThe combined extracts were washed with water
  3. washwashed with saturated brine solution
  4. dry with materialdried over magnesium sulfate
  5. concentrationThe extract was concentrated

Quellen und Nachweise

ORD-Eintrag
ord-28b93eaa005f48068dd8c1543a6e8d6e
Quelldatensatz
uspto-grants-2001_11
Patentnummer
US06313348B1

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