Acetic Acid → 2-Dodecylsulfonyl-4-chloronitrobenzene

HRID 429504

Reaktionsgleichung

Reaktionsgleichung von HRID 429504
C(O)(=O)C.[CH2:5]([S:17][C:18]1[CH:23]=[C:22]([Cl:24])[CH:21]=[CH:20][C:19]=1[N+:25]([O-:27])=[O:26])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[OH2:28].[OH:29]O>[W].O>[CH2:5]([S:17]([C:18]1[CH:23]=[C:22]([Cl:24])[CH:21]=[CH:20][C:19]=1[N+:25]([O-:27])=[O:26])(=[O:29])=[O:28])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Komponenten

6

Edukt 3

HCID 176Acetic AcidHCID 449047Hydrogen peroxide waterHCID 183562912-n-Dodecylthio-4-chloronitrobenzene

Produkt 1

HCID 183562922-Dodecylsulfonyl-4-chloronitrobenzene

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23964TungstenKatalysatorHCID 962WaterLösungsmittel

Versuchsvorschrift

0.2 g of tungsten acid sodium salt (II) hydrate was added to 40 ml of an acetic acid solution in which 17.9 g of 2-n-dodecylthio-4 -chloronitrobenzene was mixed, and 12.5 g of a 30% hydrogen peroxide water was added dropwise at an internal temperature of 70° C, and a reaction was carried out at that same temperature over three hours. The reaction solution was cooled to room temperature, and 120 ml of water was added. The precipitated crystals were filtered, washed with water and dried, and 19.5 g of 2-n-dodecylsulfonyl-4-chloronitrobenzene was obtained as a slightly yellow crystal.

Aufarbeitung

  1. additionwas mixed
  2. filtrationThe precipitated crystals were filtered
  3. washwashed with water
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-0447122ceec141118859f5e49abee20f
Quelldatensatz
uspto-grants-2001_11
Patentnummer
US06316605B1

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