Dimethyl Sulfide → Trimethylsulfonium Triflate

HRID 43293

Reaktionsgleichung

Reaktionsgleichung von HRID 43293
[CH3:1][S:2][CH3:3].[CH3:4][O:5][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:8])=[O:7]>ClCCl>[O-:8][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:7])=[O:5].[CH3:1][S+:2]([CH3:4])[CH3:3]

Komponenten

4

Edukt 2

HCID 1068Dimethyl SulfideHCID 9526Methyl triflate

Produkt 1

HCID 10933171Trimethylsulfonium Triflate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

16 mmol of dimethyl sulfide was dissolved in 10 ml of dichloromethane at 0° C., and about 17 mmol of methyltrifluoromethane sulfonate was slowly dripped to the mixture to obtain a white solid product. The solid product was filtered and dried for 1 hour in an oven at 50° C. to obtain the following product:

Aufarbeitung

  1. customto obtain a white solid product
  2. filtrationThe solid product was filtered
  3. customdried for 1 hour in an oven at 50° C.
  4. customto obtain the following product

Quellen und Nachweise

ORD-Eintrag
ord-5cc9413dfef7447db1b13d03a866a5a8
Quelldatensatz
uspto-grants-2013_09
Patentnummer
US08536347B2

Verknüpfte Notizen

Wird geladen…