Water → 4'-(2-Cyanoethylsulfonyl)acetanilide

HRID 434334

Reaktionsgleichung

Reaktionsgleichung von HRID 434334
[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11]([OH:13])=[O:12])=[CH:7][CH:6]=1)(=[O:3])[CH3:2].O.[C:15](#[N:18])[CH:16]=[CH2:17]>C(O)(=O)C>[C:15]([CH2:16][CH2:17][S:11]([C:8]1[CH:7]=[CH:6][C:5]([NH:4][C:1](=[O:3])[CH3:2])=[CH:10][CH:9]=1)(=[O:13])=[O:12])#[N:18]

Komponenten

5

Edukt 3

HCID 962WaterHCID 7855AcrylonitrileHCID 4121504-(Acetylamino)benzenesulfinic acid

Produkt 1

HCID 32390944'-(2-Cyanoethylsulfonyl)acetanilideAusbeute 68 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

A solution of 19.9 g (0.1 mol) of p-acetamidobenzenesulfinic acid (Organic Synthesis, Coll. Vol. I, page 7), 100 ml of water, 40 ml of acetic acid and 6.6 ml (0.1 mole) of acrylonitrile was heated on a steam bath for 2 hours. The resulting slurry was cooled to room temperature, filtered, washed with water and air dried to give 17.1 g (68 percent) of white solid.

Aufarbeitung

  1. filtrationfiltered
  2. washwashed with water and air
  3. customdried

Quellen und Nachweise

ORD-Eintrag
ord-5eabadff5a4145ef9c6d0c6e0316956a
Quelldatensatz
uspto-grants-1983_08
Patentnummer
US04396546

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