Nitric Acid → 5-Aminoacenaphthene

Reaktionsgleichung

[N+:1]([C:4]1[C:14]2[C:15]3[C:7]([CH2:8][CH2:9][C:10]=3[CH:11]=[CH:12][CH:13]=2)=[CH:6][CH:5]=1)([O-])=O.C1C2=C3C(=CC=C2)C=CC=C3C1.[N+]([O-])(O)=O.[Sn].NN>Cl.[Ni].C(O)C.C(O)(=O)C>[NH2:1][C:4]1[C:14]2[C:15]3[C:7]([CH2:8][CH2:9][C:10]=3[CH:11]=[CH:12][CH:13]=2)=[CH:6][CH:5]=1

Komponenten

Edukt 5

HCID 944Nitric Acid

HCID 6734Acenaphthene

HCID 9321Hydrazine

HCID 117695-Nitroacenaphthene

HCID 5352426Tin atom

Produkt 1

HCID 625475-Aminoacenaphthene

Reagenzien, Katalysatoren, Lösungsmittel 4

Versuchsvorschrift

5-Nitroacenaphthene is made by nitrating acenaphthene with nitric acid in the presence of acetic acid according to the method of Rowe and Davies, J. Chem. Soc. 117, 1346 (1920). Standard reduction methods using tin or stannous chloride in hydrochloric acid or by using Raney nickel with ethanol or hydrazine produces 5-aminoacenaphthene.