4-Toluenesulfonyl chloride → HCID 13957272, Verbindung

HRID 485299

Reaktionsgleichung

Reaktionsgleichung von HRID 485299
[C:1]1([CH3:11])[CH:6]=[CH:5][C:4]([S:7](Cl)(=[O:9])=[O:8])=[CH:3][CH:2]=1.[Cl:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][OH:21]>N1C=CC=CC=1>[C:1]1([CH3:11])[CH:6]=[CH:5][C:4]([S:7]([O:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][Cl:12])(=[O:9])=[O:8])=[CH:3][CH:2]=1

Komponenten

4

Edukt 2

HCID 73974-Toluenesulfonyl chlorideHCID 900121-Octanol, 8-chloro-

Produkt 1

HCID 13957272HCID 13957272, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1049PyridineLösungsmittel

Versuchsvorschrift

p-Toluenesulphonyl chloride (20.5 g) was added to a mixture of 8-chloro-1-octanol (17.7 g) and pyridine (50 ml) of 0°. After a hour the solution was added to ice and the mixture was extracted with ether. The ethereal solution was washed with dilute hydrochloric acid, dried with magnesium sulfate, and evaporated to yield the title compound as an oil.

Aufarbeitung

  1. additionAfter a hour the solution was added to ice
  2. extractionthe mixture was extracted with ether
  3. washThe ethereal solution was washed with dilute hydrochloric acid
  4. dry with materialdried with magnesium sulfate
  5. customevaporated

Quellen und Nachweise

ORD-Eintrag
ord-b240b72b7cec4533bb47620064d06262
Quelldatensatz
uspto-grants-1985_08
Patentnummer
US04536503

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