Styrene → Styrene 4-vinylbenzenesulfonic acid cyclohexyl ester

HRID 495332

Reaktionsgleichung

[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH:9]([C:11]1[CH:16]=[CH:15][C:14]([S:17]([OH:20])(=[O:19])=[O:18])=[CH:13][CH:12]=1)=[CH2:10].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N>C(C(C)=O)C>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH:3]1([O:19][S:17]([C:14]2[CH:13]=[CH:12][C:11]([CH:9]=[CH2:10])=[CH:16][CH:15]=2)(=[O:20])=[O:18])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]1

Komponenten

Reaktionsbedingungen

Temperatur: 65 °C

Versuchsvorschrift

A three-necked flask having a capacity of 500 ml was charged with 240 g of methyl ethyl ketone and the content was stirred at 65° C in a nitrogen gas stream. A mixture of 93.74 of styrene, 26.64 g of 4-vinylbenzenesulfonic acid cyclohe ester and 1.99 g of 2,2′-azobis(2,4-dimethylvaleronitrile) was dropwise added thereto over 2 hours. After completion of the dropwise addition, 0.5 g of 2,2′-azobis(2,4-dimethylvaleronitrile) was further added, followed by stirring for further 2 hours, thereby a styrene-4-vinylbenzenesulfonic acid cyclohexyl ester copolymer was obtained. After the reaction mixture was poured into an egg-plant type flask having a capacity of 1 liter and concentrated, 300 g of MFG was added thereto, the reaction mixture was heated for 3 hours with refluxing MFG, thereby sulfonic acid cyclohexyl ester was decomposed to obtain a sulfonic acid. The obtained reaction mixture was cooled to room temperature and poured into a beaker containing 3 liters of water, thus an aqueous solution of a high molecular compound was prepared.

Aufarbeitung

customA three-necked flask having
additionwas dropwise added
additionwas further added
stirringby stirring for further 2 hours

Quellen und Nachweise

ORD-Eintrag: ord-a4431b8c7f824b30b04ac3d80b1f5c6c
Quelldatensatz: uspto-grants-2005_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06939658B2

Verknüpfte Notizen

Wird geladen…