Cyclohexene → HCID 69796510, Verbindung

HRID 495604Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 495604
C(OC([N:11]1[CH2:15][CH2:14][CH2:13][C@@H:12]1[CH2:16][O:17][Si:18]([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19])=O)C1C=CC=CC=1.C1CCCCC=1>C(O)C.[Pd]>[Si:18]([O:17][CH2:16][C@H:12]1[CH2:13][CH2:14][CH2:15][NH:11]1)([C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:20])[CH3:19]

Komponenten

5

Edukt 2

HCID 8079CyclohexeneHCID 14629888HCID 14629888, Verbindung

Produkt 1

HCID 69796510HCID 69796510, VerbindungAusbeute 86,3 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

To a solution of D2 (12.7 g, 0.036 mol) and cyclohexene (excess, 20 ml) in ethanol (100 ml) was added 10% palladium on charcoal catalyst. Reaction was heated at reflux overnight and cooled. Catalyst was filtered and the filtrate concentrated to leave an oil (6.69 g) which was used in the next step without purification.

Aufarbeitung

  1. customReaction
  2. temperaturewas heated
  3. temperatureat reflux overnight
  4. temperaturecooled
  5. filtrationCatalyst was filtered
  6. concentrationthe filtrate concentrated

Quellen und Nachweise

ORD-Eintrag
ord-aa3eccba618748809eeaaf288611ce69
Quelldatensatz
uspto-grants-2005_09
Patentnummer
US06939891B2

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