2-Hexanol → 2-Hexyl methanesulfonate

HRID 50974

Reaktionsgleichung

[CH3:1][CH:2]([OH:7])[CH2:3][CH2:4][CH2:5][CH3:6].[CH3:8][S:9](Cl)(=[O:11])=[O:10]>>[CH3:8][S:9]([O:7][CH:2]([CH2:3][CH2:4][CH2:5][CH3:6])[CH3:1])(=[O:11])=[O:10]

Komponenten

Edukt 2

HCID 122972-Hexanol

HCID 31297Methanesulfonyl chloride

Produkt 1

HCID 153694402-Hexyl methanesulfonate

Versuchsvorschrift

The title compound was prepared by following the general procedure of Example 43 for mesylation as a colorless oil (408 mg, 68%) from 2-hexanol (312 mg, 2.90 mmol) and methanesulfonyl chloride (500 mg, 4.40 mmol). 1H NMR (CDCl3, 300 MHz) δ0.89-0.94 (m, 3H), 1.31-1.43 (m, 5H), 1.57-1.71 (m, 4H), 2.99 (s, 3H), 4.76-4.82 (m, 1H) ppm.

Quellen und Nachweise

ORD-Eintrag: ord-59f6081212b546948c3be8343fc3cd12
Quelldatensatz: uspto-grants-2004_03
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US06713471B1

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