Peracetic Acid → Peracetic Acid

HRID 567428

Reaktionsgleichung

Reaktionsgleichung von HRID 567428
[CH3:1][N:2]1[C@@H:19]2[CH2:20][C:7]3[CH:8]=[CH:9][C:10]([O:21][CH3:22])=[C:11]4[O:12][C@H:13]5[C:14]([CH:16]=[CH:17][C@@H:18]2[C@:5]5([C:6]=34)[CH2:4][CH2:3]1)=[O:15].[C:23]([O:26][OH:27])(=[O:25])[CH3:24]>CCOCC>[CH3:1][N:2]1[C@@H:19]2[CH2:20][C:7]3[CH:8]=[CH:9][C:10]([O:21][CH3:22])=[C:11]4[O:12][CH:13]5[C:14]([CH:16]=[CH:17][C@:18]2([OH:25])[C@:5]5([C:6]=34)[CH2:4][CH2:3]1)=[O:15].[C:23]([O:26][OH:27])(=[O:25])[CH3:24]

Komponenten

5

Edukt 2

HCID 6585Peracetic AcidHCID 5459910Codeinone

Produkt 2

HCID 6585Peracetic AcidHCID 5359420(4R,4aS,12bS)-4a-hydroxy-9-methoxy-3-methyl-2,4,7a,13-tetrahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7-one

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

14-Hydroxycodeinone was synthesized from the dienolsilyl ether of codeinone by oxidative hydroxylation using a peracetic acid solution preparation. The peracetic acid solution was prepared as follows:

Quellen und Nachweise

ORD-Eintrag
ord-380c0706ce624b569b2a107fe5673d80
Quelldatensatz
uspto-grants-2001_01
Patentnummer
US06177567B1

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