Methanol → Butyl 4,4-dinitropentanoate

HRID 573471

Reaktionsgleichung

Reaktionsgleichung von HRID 573471
[N+:1]([CH:4]([N+:6]([O-:8])=[O:7])[CH3:5])([O-:3])=[O:2].[OH-].[K+].[C:11]([O:15][CH2:16][CH2:17][CH2:18][CH3:19])(=[O:14])[CH:12]=[CH2:13].CO>O>[N+:1]([C:4]([N+:6]([O-:8])=[O:7])([CH3:5])[CH2:13][CH2:12][C:11]([O:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:14])([O-:3])=[O:2]

Komponenten

6

Edukt 4

HCID 887MethanolHCID 8846Butyl AcrylateHCID 14797Potassium HydroxideHCID 611501,1-Dinitroethane

Produkt 1

HCID 86717670Butyl 4,4-dinitropentanoateAusbeute 87 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel2×

Versuchsvorschrift

Dinitroethane (12 g, 0.10 mol) and potassium hydroxide (6 g, 0.11 mol) were dissolved in 100 mL of water to form a first solution. 500 mL of water was added to the first solution to dissolve a salt remaining in the first solution to form a second solution. Butyl acrylate (36 mL, 0.25 mol) was mixed with 300 mL of methanol, and then the mixture was slowly added to the second solution to form a third solution. The third solution was stirred at room temperature for 3 hours. The reaction product was extracted by diethyl ether, and was then distilled under reduced pressure to obtain yellow liquid butyl 4,4-dinitropentanoate (21.5 g, yield: 87%).

Aufarbeitung

  1. customto form a first solution
  2. dissolutionto dissolve a salt
  3. customto form a second solution
  4. additionthe mixture was slowly added to the second solution
  5. customto form a third solution
  6. extractionThe reaction product was extracted by diethyl ether
  7. distillationwas then distilled under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-f4fb369d986b4469883112d1a435e1b1
Quelldatensatz
uspto-grants-2015_05
Patentnummer
US09029591B2

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