3,5-Dimethyl-1-hexyn-3-ol → beta-CD Surfynol

HRID 5748

Reaktionsgleichung

Reaktionsgleichung von HRID 5748
[CH2:1]([OH:77])[C@H:2]1[O:7][C@@H:6]2[O:8][C@H:9]3[C@H:14]([OH:15])[C@@H:13]([OH:16])[C@@H:12]([O:17][C@H:18]4[C@H:23]([OH:24])[C@@H:22]([OH:25])[C@@H:21]([O:26][C@H:27]5[C@H:32]([OH:33])[C@@H:31]([OH:34])[C@@H:30]([O:35][C@H:36]6[C@H:41]([OH:42])[C@@H:40]([OH:43])[C@@H:39]([O:44][C@H:45]7[C@H:50]([OH:51])[C@@H:49]([OH:52])[C@@H:48]([O:53][C@H:54]8[C@H:60]([OH:61])[C@@H:59]([OH:62])[C@@H:57]([O:58][C@H:3]1[C@H:4]([OH:76])[C@H:5]2[OH:75])[O:56][C@@H:55]8[CH2:63][OH:64])[O:47][C@@H:46]7[CH2:65][OH:66])[O:38][C@@H:37]6[CH2:67][OH:68])[O:29][C@@H:28]5[CH2:69][OH:70])[O:20][C@@H:19]4[CH2:71][OH:72])[O:11][C@@H:10]3[CH2:73][OH:74].[CH3:78][CH:79]([CH2:81][C:82]([OH:86])([C:84]#[CH:85])[CH3:83])[CH3:80]>O>[CH2:67]([OH:68])[C@H:37]1[O:38][C@@H:39]2[O:44][C@H:45]3[C@H:50]([OH:51])[C@@H:49]([OH:52])[C@@H:48]([O:53][C@H:54]4[C@H:60]([OH:61])[C@@H:59]([OH:62])[C@@H:57]([O:58][C@H:3]5[C@H:4]([OH:76])[C@@H:5]([OH:75])[C@@H:6]([O:8][C@H:9]6[C@H:14]([OH:15])[C@@H:13]([OH:16])[C@@H:12]([O:17][C@H:18]7[C@H:23]([OH:24])[C@@H:22]([OH:25])[C@@H:21]([O:26][C@H:27]8[C@H:32]([OH:33])[C@@H:31]([OH:34])[C@@H:30]([O:35][C@H:36]1[C@H:41]([OH:42])[C@H:40]2[OH:43])[O:29][C@@H:28]8[CH2:69][OH:70])[O:20][C@@H:19]7[CH2:71][OH:72])[O:11][C@@H:10]6[CH2:73][OH:74])[O:7][C@@H:2]5[CH2:1][OH:77])[O:56][C@@H:55]4[CH2:63][OH:64])[O:47][C@@H:46]3[CH2:65][OH:66].[CH3:78][CH:79]([CH2:81][C:82]([OH:86])([C:84]#[CH:85])[CH3:83])[CH3:80]

Komponenten

4

Edukt 2

HCID 610183,5-Dimethyl-1-hexyn-3-olHCID 444041beta-Cyclodextrin

Produkt 1

HCID 131717491beta-CD Surfynol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

A mobile slurry is prepared by mixing about 410 g β-cyclodextrin and about 330 g deionized water (distilled water can be used) at about 25° C. in a stainless steel mixing bowl of a KitchenAid mixer using the flat beater mixing attachment. Mixing is continued while about 73 g of Perfume A is added rapidly. The low viscosity slurry immediately begins to thicken and becomes a stiff paste within a minute. Mixing is continued while 187 g of Surfynol 465 (supplied by Air Products) at about 25° C. is slowly added. This final composition is mixed until homogeneous for about 15 minutes.

Aufarbeitung

  1. customA mobile slurry is prepared
  2. additionmixing attachment
  3. additionMixing
  4. additionis added rapidly
  5. additionMixing
  6. additionis slowly added
  7. additionThis final composition is mixed until homogeneous for about 15 minutes

Quellen und Nachweise

ORD-Eintrag
ord-faa192ddc81149e4a09422705fe2de84
Quelldatensatz
uspto-grants-1993_09
Patentnummer
US05246611

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