Potassium Cyanide → HCID 13713134, Verbindung

HRID 64918

Reaktionsgleichung

Reaktionsgleichung von HRID 64918
[Br:1][C:2]([Br:12])=[CH:3][C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[CH:7]=[O:8].[C-:13]#[N:14].[K+].[Cl:16][C:17]([Cl:27])=[CH:18][CH:19]1[CH:21]([C:22](Cl)=[O:23])[C:20]1([CH3:26])[CH3:25]>CCOCC.O.[Cl-].C([N+](CC)(CC)CC1C=CC=CC=1)C>[Cl:16][C:17]([Cl:27])=[CH:18][CH:19]1[CH:21]([C:22]([O:8][CH:7]([C:13]#[N:14])[C:6]2[CH:9]=[CH:10][CH:11]=[C:4]([CH:3]=[C:2]([Br:12])[Br:1])[CH:5]=2)=[O:23])[C:20]1([CH3:26])[CH3:25]

Komponenten

7

Edukt 3

HCID 9032Potassium CyanideHCID 94551Permethric chlorideHCID 13713133HCID 13713133, Verbindung

Produkt 1

HCID 13713134HCID 13713134, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 66133Benzyl triethylammonium chlorideKatalysatorHCID 962WaterLösungsmittelHCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

In a two-phase reaction mixture, 6.1 g (0.021 mole) of 3-(2,2-dibromovinyl)-benzaldehyde in 50 ml of ether, 1.5 g (0.023 mole) of KCN in 20 ml of water, 5.0 g (0.022 mole) of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid chloride and 0.5 g of triethylbenzylammonium chloride are stirred at room temperature, and thorough mixing is continued overnight at 25° C. The phases are separated and the aqueous phase is extracted twice by shaking with ether. The ether solution is washed with sodium bisulfite, NaHCO3 and water, dried over Na2SO4 and evaporated down.

Aufarbeitung

  1. additionthorough mixing
  2. customThe phases are separated
  3. extractionthe aqueous phase is extracted twice
  4. washThe ether solution is washed with sodium bisulfite, NaHCO3 and water
  5. dry with materialdried over Na2SO4
  6. customevaporated down

Quellen und Nachweise

ORD-Eintrag
ord-3e225933de294529b6d2ce55ae8f2e32
Quelldatensatz
uspto-grants-1986_09
Patentnummer
US04611010

Verknüpfte Notizen

Wird geladen…