Benzoyl chloride → 4-Methoxybenzophenone

HRID 734191

Reaktionsgleichung

Reaktionsgleichung von HRID 734191
[C:1](Cl)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10]1([O:16][CH3:17])[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1>>[CH3:17][O:16][C:10]1[CH:15]=[CH:14][C:13]([C:1]([C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[O:8])=[CH:12][CH:11]=1

Komponenten

3

Edukt 2

HCID 7412Benzoyl chlorideHCID 7519Anisole

Produkt 1

HCID 691464-MethoxybenzophenoneAusbeute 47 %

Versuchsvorschrift

370 mg of benzoylchloride were reacted with 12 ml anisole to give the benzoylated product 4-methoxybenzophenone in 47% yield. The catalyst used is a HS—AlF3 metal fluoride on a Al2O3 support prepared according to the present invention, which is used in an amount of 300 mg. The reaction is carried out in a discontinuous batch process at 60° C. under reflux with stirring.

Quellen und Nachweise

ORD-Eintrag
ord-a14a8e7438594020a2313d82de28bc73
Quelldatensatz
uspto-grants-2009_09
Patentnummer
US07592287B2

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