Water → 6-Butylbenzo[b]quinolizinium perchlorate

HRID 742490Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 742490
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].CO[C:8]1[C:17]2[CH:16]=[C:15]3[CH:18]=[CH:19][CH:20]=[CH:21][C:14]3=[CH:13][N+:12]=2[CH:11]=[CH:10][CH:9]=1.O.Cl([O-])(=O)(=O)=O.[Na+]>Br>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH2:17]([C:13]1[N+:12]2[CH:11]=[CH:10][CH:9]=[CH:8][C:17]=2[CH:16]=[C:15]2[CH:18]=[CH:19][CH:20]=[CH:21][C:14]=12)[CH2:8][CH2:9][CH3:10]

Komponenten

5

Edukt 3

HCID 962WaterHCID 522606Sodium PerchlorateHCID 151862871-Methoxybenzo[b]quinolizinium perchlorate

Produkt 1

HCID 190474766-Butylbenzo[b]quinolizinium perchlorateAusbeute 156,2 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 260Hydrogen BromideLösungsmittel

Reaktionsbedingungen

Temperatur
100 °C

Versuchsvorschrift

A mixture of 1-methoxybenzo[b]quinolizinium perchlorate (1.4 g; 6.1 mmol) in 30 ml of 48% HBr was heated at 100° C. for 16 hour. The reaction mixture was poured into 100 ml of water and 50 ml of sodium perchlorate was added with stirring. The resulting solid was filtered and dried to afford 1.6 g (88.8%) of 1-hydroxybenzo[b]quinolizinium perchlorate (Formula II: R1 =1--OH; R2 =R3 =H; X- =ClO4-) as a solid.

Aufarbeitung

  1. additionwas added
  2. filtrationThe resulting solid was filtered
  3. customdried

Quellen und Nachweise

ORD-Eintrag
ord-0f48b2e88a4f4342a5d0d207fe20ae8c
Quelldatensatz
uspto-grants-1996_09
Patentnummer
US05554620

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